Close Menu
Fund Focus News
    Facebook X (Twitter) Instagram
    Trending
    • A Fund That Buys Recent IPO Stocks: Should You Invest?
    • Zee Business Mutual Fund Awards 2025: From ICICI to SBI, major AMCs shine as industry celebrates Rs 75 lakh crore milestone
    • Back to basics: Multi-factor mutual funds in India
    • Zee Business Mutual Fund Awards 2025: Industry leaders, top fund houses honoured across 9 categories
    • Private-credit ETFs are here. Why your -2-
    • Best mutual Fund types for retirement planning – Money Insights News
    • Spot Bitcoin ETFs See $812M Outflow as Ether ETFs Break 20-Day Inflow Streak
    • SECP launches strategic steps to transform mutual funds industry – Business & Finance
    Facebook X (Twitter) Instagram
    Fund Focus News
    • Home
    • Bonds
    • ETFs
    • Funds
    • Investments
    • Mutual Funds
    • Property Investments
    • SIP
    Fund Focus News
    Home»Bonds»Direct oxygen insertion into C-C bond of styrenes with air
    Bonds

    Direct oxygen insertion into C-C bond of styrenes with air

    October 18, 2024


  • Jurczyk, J. et al. Single-atom logic for heterocycle editing. Nat. Synth. 1, 352–364 (2022).

    Article 
    ADS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Wang, H. et al. Dearomative ring expansion of thiophenes by bicyclobutane insertion. Science 381, 75–81 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Patel, S. C. & Burns, N. Z. Conversion of aryl azides to aminopyridines. J. Am. Chem. Soc. 144, 17797–17802 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Pearson, T. J. et al. Aromatic nitrogen scanning by ipso-selective nitrene internalization. Science 381, 1474–1479 (2023).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Woo, J., Stein, C., Christian, A. H. & Levin, M. D. Carbon-tonitrogen single-atom transmutation of azaarenes. Nature 623, 77–82 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Nguyen, H. M. H. et al. Synthesis of 15N-Pyridines and higher mass isotopologs via Zincke Imine intermediates. J. Am. Chem. Soc. 146, 2944–2949 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Tolchin, Z. A. & Smith, J. M. 15NRORC: An azine labeling protocol. J. Am. Chem. Soc. 146, 2939–2943 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Jurczyk, J. et al. Photomediated ring contraction of saturated heterocycles. Science 373, 1004–1012 (2021).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Cheng, Q. et al. Skeletal editing of pyridines through atom-pair swap from CN to CC. Nat. Chem. 16, 741–748 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Lyu, H., Kevlishvili, I., Yu, X., Liu, P. & Dong, G. Boron insertion into alkyl ether bonds via Zinc/Nickel tandem catalysis. Science 372, 175–182 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, X. et al. Angew. Chem. Int. Ed. 63, e202318613 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Dherange, B. D., Kelly, P. Q., Liles, J. P., Sigman, M. S. & Levin, M. D. Carbon atom insertion into pyrroles and indoles promoted by chlorodiazirines. J. Am. Chem. Soc. 143, 11337–11344 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Hyland, E. E., Kelly, P. Q., McKillop, A. M., Dherange, B. D. & Levin, M. D. Unified access to pyrimidines and quinazolines enabled by N−N cleaving carbon atom insertion. J. Am. Chem. Soc. 144, 19258–19264 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Piacentini, P., Bingham, T. W. & Sarlah, D. Dearomative ring expansion of polycyclic arenes. Angew. Chem., Int. Ed. 61, e202208014 (2022).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Joynson, B. W., Cumming, G. R. & Ball, L. T. Photochemically mediated ring expansion of indoles and pyrroles with chlorodiazirines: synthetic methodology and thermal hazard assessment. Angew. Chem., Int. Ed. 62, e202305081 (2023).

    Article 

    Google Scholar
     

  • Fujimoto, H., Nakayasu, B. & Tobisu, M. Synthesis of γ-Lactams from acrylamides by single-carbon atom doping annulation. J. Am. Chem. Soc. 145, 19518–19522 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Li, L. et al. Dearomative Insertion of fluoroalkyl carbenes into azoles leading to fluoroalkyl heterocycles with a quaternary center. Angew. Chem. Int. Ed. 63, e202313807 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Kelly, P. Q., Filatov, A. S. & Levin, M. D. A synthetic cycle for heteroarene synthesis by nitride insertion. Angew. Chem., Int. Ed. 61, e202213041 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Reisenbauer, J. C., Green, O., Franchino, A., Finkelstein, P. & Morandi, B. Late-stage diversification of indole skeletons through nitrogen atom insertion. Science 377, 1104–1109 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Boudry, E., Bourdreux, F., Marrot, J., Moreau, X. & Ghiazza, C. Dearomatization of pyridines: photochemical skeletal enlargement for the synthesis of 1,2-Diazepines. J. Am. Chem. Soc. 146, 2845–2854 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, J., Lu, H., He, Y., Jing, C. & Wei, H. Cobalt-catalyzed nitrogen atom insertion in arylcycloalkenes. J. Am. Chem. Soc. 144, 22433–22439 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Bartholomew, G. L., Carpaneto, F. & Sarpong, R. Skeletal editing of pyrimidines to pyrazoles by formal carbon deletion. J. Am. Chem. Soc. 144, 22309–22315 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Woo, J. et al. Scaffold hopping by net photochemical carbon deletion of azaarenes. Science 376, 527–532 (2022).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Kennedy, S. H., Dherange, B. D., Berger, K. J. & Levin, M. D. Skeletal editing through direct nitrogen deletion of secondary amines. Nature 593, 223–227 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Hui, C., Brieger, L., Strohmann, C. & Antonchick, A. P. Stereoselective synthesis of cyclobutanes by contraction of pyrrolidines. J. Am. Chem. Soc. 143, 18864–18870 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Qin, H. et al. N-atom deletion in nitrogen heterocycles. Angew. Chem. Int. Ed. 60, 20678–20683 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Wright, B. A. et al. Skeletal editing approach to bridge-functionalized Bicyclo[1.1.1]pentanes from Azabicyclo[2.1.1]hexanes. J. Am. Chem. Soc. 145, 10960–10966 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Cao, Z.-C. & Shi, Z.-J. Deoxygenation of ethers to form carbon-carbon bonds via nickel catalysis. J. Am. Chem. Soc. 139, 6546–6549 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Evano, G., Wang, J. & Nitelet, A. Metal-mediated C-O bond forming reactions in natural product synthesis. Org. Chem. Front. 4, 2480–2499 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Enthaler, S. & Company, A. Palladium-catalysed hydroxylation and alkoxylation. Chem. Soc. Rev. 40, 4912–4924 (2011).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Roughley, S. D. & Jordan, A. M. The medicinal chemist’s toolbox: An analysis of reactions used in the pursuit of drug candidates. J. Med. Chem. 54, 3451–3479 (2011).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Kelley, B. T., Walters, J. C. & Wengryniuk, S. E. Access to diverse oxygen heterocycles via oxidative rearrangement of benzylic tertiary alcohols. Org. Lett. 18, 1896–1899 (2016).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Baeyer, A. & Villiger, V. Reactivity of Caro’s reagents with ketones. Ber. Dtsch. Chem. Ges. 32, 3625–3633 (1899).

    Article 

    Google Scholar
     

  • Baeyer, A. & Villiger, V. On the reactivity of Caro’s reagents with ketones. Ber. Dtsch. Chem. Ges. 33, 858–864 (1900).

    Article 
    CAS 

    Google Scholar
     

  • Siddiqi, Z., Wertjes, W. C. & Sarlah, D. Chemical equivalent of arene monooxygenases: dearomative synthesis of arene oxides and oxepines. J. Am. Chem. Soc. 142, 10125–10131 (2020).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Wu, W. & Jiang, H. Palladium catalyzed oxidation of unsaturated hydrocarbons using molecular oxygen. Acc. Chem. Res. 45, 1736–1748 (2012).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Tang, C., Qiu, X., Cheng, Z. & Jiao, N. Molecular oxygen-mediated oxygenation reactions involving radicals. Chem. Soc. Rev. 50, 8067–8101 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Punniyamurthy, T., Velusamy, S. & Iqbal, J. Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen. Chem. Rev. 105, 2329–2363 (2005).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Liang, Y.-F. & Jiao, N. Oxygenation via C−H/C−C bond activation with molecular oxygen. Acc. Chem. Res. 50, 1640–1653 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, D., Weinstein, A. B., White, P. B. & Stahl, S. S. Ligand promoted palladium-catalyzed aerobic oxidation reactions. Chem. Rev. 118, 2636–2679 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Vaughan, B. A., Webster-Gardiner, M. S., Cundari, T. R. & Gunnoe, T. B. A rhodium catalyst for single-step styrene production from benzene and ethylene. Science 348, 421–424 (2015).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Baumann, H. et al. Natural fats and oils-renewable raw Materials for the chemical industry. Angew. Chem. Int. Ed. 27, 41–62 (1988).

    Article 
    ADS 

    Google Scholar
     

  • Corma, A., Iborra, S. & Velty, A. Chemical routes for the transformation of biomass into chemicals. Chem. Rev. 107, 2411–2502 (2007).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Smidt, J. et al. The oxidation of olefins with palladium chloride catalysts. Angew. Chem., Int. Ed. 1, 80–88 (1962).

    Article 

    Google Scholar
     

  • Jira, R. Acetaldehyde from Ethylene-A retrospective on the discovery of the Wacker process. Angew. Chem., Int. Ed. 48, 9034–9037 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Hess, J. S., Leelasubcharoen, S., Rheingold, A. L., Doren, D. J. & Theopold, K. H. Spin surface crossing in chromium-mediated Olefin Epoxidation with O2. J. Am. Chem. Soc. 124, 2454–2455 (2002).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Schröder, K. et al. A biomimetic iron catalyst for the Epoxidation of Olefins with molecular oxygen at room temperature. Angew. Chem., Int. Ed. 50, 1425–1429 (2011).

    Article 

    Google Scholar
     

  • Koya, S., Nishioka, Y., Mizoguchi, H., Uchida, T. & Katsuki, T. Asymmetric Epoxidation of conjugated Olefins with dioxygen. Angew. Chem., Int. Ed. 51, 8243–8246 (2012).

    Article 
    CAS 

    Google Scholar
     

  • Zhu, B. et al. Selective aerobic oxygenation of tertiary allylic alcohols with molecular oxygen. Angew. Chem. Int. Ed. 58, 11028–11032 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Urgoitia, G., SanMartin, R., Herrero, M. T. & Dominguez, E. Aerobic cleavage of alkenes and alkynes into carbonyl and carboxyl compounds. ACS Catal. 7, 3050–3060 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Rajagopalan, A., Lara, M. & Kroutil, W. Oxidative alkene cleavage by chemical and enzymatic methods. Adv. Synth. Catal. 355, 3321–3335 (2013).

    Article 
    CAS 

    Google Scholar
     

  • Nakamura, A. & Nakada, M. Allylic oxidations in natural product synthesis. Synthesis 45, 1421–1451 (2013).

    Article 
    CAS 

    Google Scholar
     

  • Catino, A. J., Forslund, R. E. & Doyle, M. P. Dirhodium(II) Caprolactamate: An exceptional catalyst for allylic oxidation. J. Am. Chem. Soc. 126, 13622–13623 (2004).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yu, J.-Q. & Corey, E. J. A mild, catalytic, and highly selective method for the oxidation of α,β-Enones to 1,4-Enediones. J. Am. Chem. Soc. 125, 3232–3233 (2003).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, Y., Chen, X., Jin, H. & Wang, Y. Mild and Practical Dirhodium(II)/NHPI-mediated allylic and benzylic oxidations with air as the oxidant. Chem. -Eur. J. 25, 14273–14277 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Horn, E. J. et al. Scalable and sustainable electrochemical allylic C−H oxidation. Nature 533, 77–81 (2016).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Liu, C. et al. Visible-light-enabled allylic C−H Oxidation: metal-free photocatalytic generation of enones. ACS Catal. 12, 1375–1381 (2022).

    Article 

    Google Scholar
     

  • Jiang, Y., Chen, S., Chen, Y., Gu, A. & Tang, C. Sustainable aerobic allylic C−H bond oxidation with heterogeneous iron catalyst. J. Am. Chem. Soc. 146, 2769–2778 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Youn, S. W., Kim, B. S. & Jagdale, A. R. Pd-catalyzed sequential C-C bond formation and cleavage: evidence for an unexpected generation pf Arylpalladium(II) species. J. Am. Chem. Soc. 134, 11308–11311 (2012).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Ye, J. et al. Remote C-H alkylation and C-C bond cleavage enabled by an in situ generated palladacycle. Nat. Chem. 9, 361–368 (2017).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, J. J., Wei, D. H., Duan, Z. & Mathey, F. Cleavage of the Inert C(sp2)-Ar σ-bond of alkenes by a spatial constrained interaction with Phosphinidene. J. Am. Chem. Soc. 142, 20973–20978 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Liu, J. et al. Selective Dealkenylative functionalization of styrenes via C-C bond cleavage. Research 2020, 7947029 (2020).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Lasso, J. D. et al. A general platform for visible light sulfonylation reactions enabled by catalytic Triarylamine EDA complexes. J. Am. Chem. Soc. 146, 2583–2592 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhao, G., Lim, S., Musaev, D. G. & Ngai, M. Y. Expanding reaction profile of allyl carboxylates via 1,2-Radical Migration (RaM): Visible-light-induced phosphine-catalyzed 1,3-Carbobromination of Allyl carboxylates. J. Am. Chem. Soc. 145, 8275–8284 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Chen, Z.-M., Zhang, X.-M. & Tu, Y.-Q. Radical aryl migration reactions and synthetic applications. Chem. Soc. Rev. 44, 5220–5245 (2015).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Studer, A. & Bossart, M. Radical aryl migration reactions. Tetrahedron 57, 9649–9667 (2001).

    Article 
    CAS 

    Google Scholar
     

  • Smeu, M. & DiLabio, G. A. Rearrangement of the 1,1-Diphenylethoxyl radical is not concerted but occurs through a bridged intermediate. J. Org. Chem. 72, 4520–4523 (2007).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Salamone, M., Bietti, M., Calcagni, A. & Gente, G. Phenyl bridging in ring-substituted cumyloxyl radicals. a product and time-resolved kinetic study. Org. Lett. 11, 2453–2456 (2009).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Bietti, M., Calcagni, A., Cicero, D. O., Martella, R. & Salamone, M. The O-neophyl rearrangement of 1,1-diarylalkoxyl radicals. Experimental evidence for the formation of an intermediate 1-oxaspiro[2,5]octadienyl radical. Tetrahedron Lett. 51, 4129–4131 (2010).

    Article 
    CAS 

    Google Scholar
     



  • Source link

    Share. Facebook Twitter Pinterest LinkedIn Tumblr Telegram Email

    Related Posts

    Should UK-based clients still own US government bonds? 

    August 1, 2025

    Japanese bonds log weekly foreign outflows on BOJ policy caution

    July 30, 2025

    What Are Bonds? A Beginner’s Guide (2025)

    July 30, 2025
    Leave A Reply Cancel Reply

    Top Posts

    A Fund That Buys Recent IPO Stocks: Should You Invest?

    August 2, 2025

    Qu’est-ce qu’un green bond ?

    December 7, 2017

    les cat’ bonds deviennent incontournables

    September 5, 2018

    ETF : définition et intérêt des trackers

    May 15, 2019
    Don't Miss
    Mutual Funds

    A Fund That Buys Recent IPO Stocks: Should You Invest?

    August 2, 2025

    The primary markets have been buzzing with many companies coming with new issues. Some of…

    Zee Business Mutual Fund Awards 2025: From ICICI to SBI, major AMCs shine as industry celebrates Rs 75 lakh crore milestone

    August 2, 2025

    Back to basics: Multi-factor mutual funds in India

    August 2, 2025

    Zee Business Mutual Fund Awards 2025: Industry leaders, top fund houses honoured across 9 categories

    August 2, 2025
    Stay In Touch
    • Facebook
    • Twitter
    • Pinterest
    • Instagram
    • YouTube
    • Vimeo
    EDITOR'S PICK

    What are Index Funds and ETFs?

    May 21, 2025

    Is property investment still as safe as houses?

    July 1, 2025

    NFO Alert: HDFC Mutual Fund launches innovation-themed fund

    June 26, 2025
    Our Picks

    A Fund That Buys Recent IPO Stocks: Should You Invest?

    August 2, 2025

    Zee Business Mutual Fund Awards 2025: From ICICI to SBI, major AMCs shine as industry celebrates Rs 75 lakh crore milestone

    August 2, 2025

    Back to basics: Multi-factor mutual funds in India

    August 2, 2025
    Most Popular

    ₹10,000 monthly SIP in this debt mutual fund has grown to over ₹70 lakh in 23 years

    June 13, 2025

    ₹1 lakh investment in these 2 ELSS mutual funds at launch would have grown to over ₹5 lakh. Check details

    April 25, 2025

    ZIG, BUZZ, NANC, and KRUZ

    October 11, 2024
    © 2025 Fund Focus News
    • Get In Touch
    • Privacy Policy
    • Terms and Conditions

    Type above and press Enter to search. Press Esc to cancel.